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Chemistry · Grades 10–12

Diprotic-acid stoichiometry

Use the balanced equation, not an assumed one-to-one ratio. Here each formula unit supplies two hydroxide ions.

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Rule and assumptions

Use the balanced equation, not an assumed one-to-one ratio. Here each formula unit supplies two hydroxide ions.

H₂A + 2OH⁻ → A²⁻ + 2H₂O; n(OH⁻) = 2n(H₂A)

Worked examples

In the supplied complete neutralization equation H₂A + 2OH⁻ → A²⁻ + 2H₂O, how much OH⁻ reacts with 0.5 mol H₂A? Round to 3 decimal places if needed. Answer in mol.

H₂A + 2OH⁻ → A²⁻ + 2H₂O; n(OH⁻) = 2n(H₂A) 2 × 0.5 = 1

1 mol

In the supplied complete neutralization equation H₂A + 2OH⁻ → A²⁻ + 2H₂O, how much OH⁻ reacts with 0.09 mol H₂A? Round to 3 decimal places if needed. Answer in mol.

H₂A + 2OH⁻ → A²⁻ + 2H₂O; n(OH⁻) = 2n(H₂A) 2 × 0.09 = 0.18

0.18 mol

Try two questions

  1. In the supplied complete neutralization equation H₂A + 2OH⁻ → A²⁻ + 2H₂O, how much OH⁻ reacts with 0.01 mol H₂A? Round to 3 decimal places if needed. Answer in mol.

  2. In the supplied complete neutralization equation H₂A + 2OH⁻ → A²⁻ + 2H₂O, how much OH⁻ reacts with 0.34 mol H₂A? Round to 3 decimal places if needed. Answer in mol.

Answers and reasoning

Answers and marking notes
  1. 0.02 mol

    H₂A + 2OH⁻ → A²⁻ + 2H₂O; n(OH⁻) = 2n(H₂A) 2 × 0.01 = 0.02

  2. 0.68 mol

    H₂A + 2OH⁻ → A²⁻ + 2H₂O; n(OH⁻) = 2n(H₂A) 2 × 0.34 = 0.68

Further reading and review references

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Learning preview · independent educational and translation review required. Suggested grades are not official curriculum alignment.