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Chemistry · Grades 10–12

Bond-enthalpy estimate

Bond breaking requires energy; bond formation releases it. Average bond energies give an approximate reaction enthalpy.

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Rule and assumptions

Bond breaking requires energy; bond formation releases it. Average bond energies give an approximate reaction enthalpy.

ΔH ≈ bonds broken − bonds formed

Worked examples

For one reaction as written, a bond model requires 463 kJ/mol to break bonds and releases 756 kJ/mol on forming bonds. Estimate ΔH. Round to 3 decimal places if needed. Answer in kJ/mol.

ΔH ≈ bonds broken − bonds formed 463 − 756 = -293

-293 kJ/mol

For one reaction as written, a bond model requires 1048 kJ/mol to break bonds and releases 854 kJ/mol on forming bonds. Estimate ΔH. Round to 3 decimal places if needed. Answer in kJ/mol.

ΔH ≈ bonds broken − bonds formed 1048 − 854 = 194

194 kJ/mol

Try two questions

  1. For one reaction as written, a bond model requires 1188 kJ/mol to break bonds and releases 1176 kJ/mol on forming bonds. Estimate ΔH. Round to 3 decimal places if needed. Answer in kJ/mol.

  2. For one reaction as written, a bond model requires 361 kJ/mol to break bonds and releases 849 kJ/mol on forming bonds. Estimate ΔH. Round to 3 decimal places if needed. Answer in kJ/mol.

Answers and reasoning

Answers and marking notes
  1. 12 kJ/mol

    ΔH ≈ bonds broken − bonds formed 1188 − 1176 = 12

  2. -488 kJ/mol

    ΔH ≈ bonds broken − bonds formed 361 − 849 = -488

Further reading and review references

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Learning preview · independent educational and translation review required. Suggested grades are not official curriculum alignment.